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Title:Reaction Kinetics of Photoredox Cross Couplings with Dr. Yael Ben-Tal
Duration:22:19
Viewed:2,530
Published:03-02-2023
Source:Youtube

In this Research Spotlight episode, Dr. Yael Ben-Tal (Lloyd-Jones group, University of Edinburgh) joins us to share her work on the kinetics of a photoredox cross coupling using nickel and iridium. Key reference: J. Am. Chem. Soc. 2022, 144, 15372–15382. https://doi.org/10.1021/jacs.2c06831 Other references (in order of appearance): Original publications: Science. 2014, 345, 433-436.; Science. 2014, 345, 437-440. Selected recent reviews: Chem. Rev. 2022, 122, 1485-1542.; Wiley Interdiscip. Rev. Comput. Mol. Sci. 2021, 12, e1573.; Angew. Chem. Int. Ed. 2019, 58, 6152-6163.; Eur. J. Org. Chem., 2020, 1327-1378. Previous kinetic study: J. Am. Chem. Soc. 2020, 142, 11042-11049. This design is adapted from that developed in J. Magn. Reson. 2013, 232, 39−44. Original reaction developed in J. Am. Chem. Soc. 2016, 138, 8084-8087. For more about isotope labelling in mechanistic study see Prog. Nucl. Magn. Reson. Spectrosc. 2022, 129, 28-106.



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